The Avengers (1998)

http://www.imdb.com/title/tt0118661/

British Ministry agent John Steed (Ralph Fiennes), under direction from "Mother", investigates a diabolical plot by arch-villain Sir August de Wynter (Sean Connery) to rule the world with his weather control machine. Steed investigates the beautiful Doctor Mrs. Emma Peel (Uma Thurman), the only suspect, but simultaneously falls for her and joins forces with her to combat Sir August.

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